Tabla 3-7. CONSTANTES a, b, c y d PARA LA EXPANSIÓN POLINOMICA DE TERCER ORDEN QUE DA LA CAPACIDAD CALORÍFICA EN FUNCIÓN DE LA TEMPERATURA .
COMPUESTO |
A |
b x 102 |
c x l05 |
d x 109 |
INTERVALO KELVIN |
ERROR MEDIO |
Metano |
4.750 |
1.200 |
0.3030 |
-2 .630 |
273-1500 |
0.57 |
Etano |
1.648 |
4.124 |
-1.53 0 |
1.740 |
|
0.28 |
Propano |
-0.966 |
7.279 |
-3.755 |
7.580 |
|
0.12 |
n-Butano |
0.945 |
8.873 |
-4.380 |
8.360 |
|
0.24 |
Isobutano |
-1.890 |
9.936 |
-5.495 |
11.920 |
|
0.13 |
neo-Pentano |
-3.865 |
13.305 |
-8.018 |
18.830 |
|
0.12 |
neo-Hexano |
1.657 |
13.190 |
-6.844 |
13.780 |
|
0.20 |
Etileno |
0.944 |
3.735 |
-1.993 |
4.220 |
- |
0.13 |
Propileno |
0.753 |
5.691 |
-2.910 |
5,880 |
|
0.17 |
1-Buteno |
-0.240 |
5.650 |
-5.110 |
12 .070 |
|
0.18 |
Isobuteno |
1.650 |
7.702 |
-3.981 |
8.020 |
|
0.06 |
Cis-2-Buteno |
-1.778 |
8.078 |
-4.074 |
7.890 |
|
0.14 |
Trans-2-Buteno |
2.340: |
17.220 |
-3.403 |
6.070 |
|
0.12 |
Ciclopentano |
-12.957' |
13,087 |
-7.447 |
16.410 |
|
0.25 |
Metilciclopentano |
-12.114 |
'15.380 |
-8.915 |
20.030 |
|
0.23 |
Ciclo-Hexano |
-15.935 |
16.454 |
-9.203 |
19.270 |
|
0.37 |
Metilciclohexano |
-15.070 |
18.972 |
-10.989 |
2 4.090 |
|
0.22 |
Benceno |
-8.650 |
11.578 |
-7.540 |
18.540 |
|
0.20 |
Tolueno |
-8.213 |
13.357 |
-8.230 |
19,200 |
|
0.18 |
Etilbenceno |
-8.398 |
15.935 |
-10.003 |
23.95 |
|
0.19 |
Estireno |
-5.968 |
14.354 |
-9.150 |
22.030 |
|
0.23 |
cumeno |
-9.452 |
1S.686 |
-11.869 |
28.800 |
|
0.17 |
Acetileno |
5.210 |
2 .2008 |
-1.559 |
4.349 |
|
0.59 |
Metilacetileno |
4.210 |
4.073 |
-2.192 |
4.713 |
|
0.13 |
Dimetilacetileno |
3.540 |
5.838 |
-2.760 |
4.974 |
|
0.16 |
Propanodieno |
2.430 |
4.693 |
-2.781 |
6,484 |
|
0.19 |
1,3-Butadieno |
-1.290 |
8.350 |
-5.582 |
14.240 |
|
0.47 |
Isopreno |
-0.440 |
10.418 |
-6.762 |
16.930 |
|
0.43 |
Nitrógeno |
6,903 |
-0.03753 |
0.193 |
-0.6861 |
273-1800 |
0,34 |
Oxígeno |
6.085 |
0.3631 |
-0.1709 |
0.3133 |
|
0.28 |
Aire |
6.713 |
0.04697 |
0.1147 |
-0.4696 |
|
0.33 |
Hidrógeno |
6.952 |
-0.04576 |
0.09563 |
-0.2079 |
|
0.26 |
Monóxido de carbono |
9.726 |
0.04001 |
0,1283 |
-0.5307 |
|
0.3? |
Dióxido de carbono |
5.316 |
1.4285 |
-0.8362 |
1 .784 |
|
0.22 |
Vapor de agua |
7.700 |
0.04594 |
0.2 521 |
-0.8587 |
|
0.24 |
Nitrógeno |
S.529 |
0.1488 |
-0.02271 |
|
273-3800 |
0.72 |
Oxigeno |
6,732 |
0.1505 |
-0.01791 |
|
|
1 .20 |
Hidrógeno |
6.424 |
0.1039 |
-0.007804 |
|
|
0.79 |
Aire |
6.557 |
0.1477 |
-0.02148 |
|
|
0 ,70 |
Monóxido de Carbono |
6.480 |
0.1566 |
-0.02387 |
|
|
1.01 |
Vapor de Agua |
6.970 |
0.3464 |
-0.O4S33 |
|
|
0.66 |
Azufre, 22 |
6.499 |
0.5298 |
-0.3888 |
0,9520 |
273-1800 |
0.38 |
Anhídrido sulfuroso |
6.157 |
1.384 |
-0.9103 |
2.057 |
|
0.24 |
Anhídrido sulfúrico |
3.918 |
3.483 |
-2.675 |
7.744 |
273-1300 |
0,13 |
Acido sulfhídrico |
7.070 |
0.3128 |
0.1364 |
-0.7867 |
273-1800 |
0.37 |
Sulfuro de carbono |
7.390 |
1 .489 |
-1.096 |
2 .760 |
|
0.47 |
Sulfuro de carbonilo |
6.222 |
1 .536 |
-1.058 |
2.560 |
|
0.49 |
Flúor |
6.115 |
0.5864 |
-0.4186 |
0.9797 |
273-2000 |
0.45 |
Cloro |
6.8214 |
0.57095 |
-0.5107 |
1.547 |
273-1500 |
0.23 |
Bromo |
8.051 |
0.2462 |
-0.2128 |
0.6406 |
» |
0.15 |
Yodo |
8.504 |
0.13135 |
-0.10684 |
0,3125 |
273-1800 |
0.06 |
Fluoruro de hidrógeno |
7.201 |
-0.1178 |
0.1576 |
-0.376 |
273-2000 |
0.09 |
Cloruro de hidrógeno |
7.244 |
-0.1820 |
0.3170 |
-1.036 |
273-1500 |
0 .08 |
Bromuro de hidrógeno |
7.169 |
-0.1604 |
0.3314 |
-1.161 |
|
0.12 |
Yoduro de hidrógeno |
6.702 |
0.04546 |
0.1216 |
-0.4813 |
273-1900 |
0.39 |
Cloruro de metilo |
3.050 |
2.596 |
-1.244 |
2 .300 |
273-1500 |
0.16 |
Cloruro de metileno |
4.200 |
3.419 |
2.350 |
6.068 |
|
0.30 |
Cloroformo |
7.610 |
3 .461 |
-2.668 |
7.344 |
|
0.42 |
Tetracloruro de carbono |
12.24 |
3 .400 |
-2.995 |
8.828 |
|
0.57 |
Fosgeno |
10.350 |
1.653 |
-0.8408 |
|
273-1000 |
0.46 |
Tiofosgeno |
10.800 |
1.859 |
-1.045 |
|
|
0.71 |
Cianógeno |
9 ,820 |
1 ,4858 |
-0.6571 |
|
|
0 .42 |
Cianuro de hidrógeno |
6,34 |
0.8375 |
-0.2611 |
|
273-1500 |
0.76 |
Cloruro de cianógeno |
7,97 |
0.0745 |
-0.5265 |
|
273-1000 |
0.58 |
Bromuro de cianógeno |
8.82 |
0.9084 |
-0.4367 |
|
|
0.54 |
Yoduro de cianógeno |
9.69 |
0.7213 |
-0.3265 |
|
|
0.37 |
Acetonitrilo |
5.09 |
2 .7634 |
-0.9111 |
|
273-1200 |
0.26 |
Nitrilo acrílico |
4.55 |
4.1039 |
-1.6939 |
|
273-1000 |
0.41 |
Oxido nítrico |
6.461 |
0.2358 |
-0.07705 |
0.08729 |
273-3800 |
0.54 |
Oxido nítrico |
7.008 |
-0.02244 |
0.2328 |
1 .000 |
273-1500 |
0.36 |
Oxido nitroso |
5.758 |
1.4004 |
-0.55008 |
2.526 |
|
0.26 |
Dióxido de nitrógeno |
5.48 |
1.365 |
-0.841 |
1 .88 |
|
0.18 |
Tetróxido de nitrógeno |
7.90 |
4 .46 |
-2.71 |
|
273-600 |
0.36 |
Formaldehido |
5.447 |
0.9739 |
0.1703 |
-2.078 |
273-1500 |
0.62 |
Acetaldehído |
4.19 |
3.164 |
-0.515 |
-3.800 |
273-1000 |
0.17 |
Metanol |
4.55 |
2.186 |
-0.291 |
-1.920 |
|
0.08 |
Etanol |
4.75 |
5.006 |
-2.479 |
4.790 |
273-1500 |
0.22 |
Oxido de etileno |
-1.12 |
4.925 |
-2.389 |
3 .149 |
273-1000 |
0 .14 |
Ceteno |
4.11 |
2.966 |
-1.793 |
4.22 |
273-1500 |
0.17 |
Ciclopropano |
-6.481 |
8.206 |
-5.577 |
15.61 |
273-1000 |
0.35 |
Isopentano |
-2.273 |
12.434 |
-7.097 |
15.86 |
273-1500 |
0.14 |
o-Xileno |
-3.789 |
14.291 |
-8.354 |
18.80 |
|
0.15 |
m-Xileno |
-6.533 |
14.905 |
-8.831 |
20.05 |
|
0.16 |
p-Xileno |
-5.334 |
14.220 |
-7.984 |
17.03 |
|
0.18 |
Monóxido de carbono |
8.203 |
3 .073 |
-2.081 |
5.182 |
|
0.31 |
Acetona |
1 .625 |
6.661 |
-3.737 |
S.307 |
|
0.10 |
Alcohol isopropílioo |
0.7936 |
8.502 |
-5.016 |
11.56 |
|
0,18 |
Alcohol neopropílico |
-1.307 |
9.235 |
-5.800 |
14.14 |
|
0.30 |
Alcohol alílico |
0.5203 |
7.122 |
-4.259 |
9.948 |
|
0.14 |
Cloroetano |
2.401 |
4.27 |
-2.751 |
6.797 |
|
0.22 |
1,1-dicloroetano |
5.899 |
4.383 |
-3.182 |
8.516 |
|
0.40 |
cis-1,2 - dicloroetano |
4.336 |
4.691 |
-3.397 |
9.010 |
|
0.39 |
Trans-1,2-dicloroetano |
5.6 61 |
4.295 |
-3.022 |
7.891 |
|
0.27 |
Tricloroetano |
9.200 |
4.517 |
-3.600 |
10.10 |
|
0.50 |
Tetracloroetano |
15.11 |
3.799 |
-3.179 |
9.089 |
|
0.42 |
Amoníaco |
6-5846 |
0.61251 |
0.23663 |
-1.5981 |
|
0.3S |
Hidracina |
3 .890 |
3 .554 |
-2.304 |
5.990 |
|
0.50 |
Metilamina |
2.9956 |
3 .6101 |
-1.6446 |
2 .9505 |
|
0.07 |
Dimetilamina |
-0.275 |
6.6152 |
-3.4826 |
7.1510 |
|
0.15 |
Trimetilamina |
-2.098 |
9.6187 |
-5.5488 |
12.432 |
|
0 .18 |
Tabla 3-8.CONSTANTES a, b, c y d PARA LA EXPANSIÓN POLINOMICA DE TERCER ORDEN QUE DA LA CAPACIDAD CALORÍFICA EN FUNCIÓN DE LA TEMPERATURA.
COMPUESTO |
a |
b x 103 |
c x 103 |
d x 109 |
INTERVALO |
Peróxido de hidrógeno |
5.52 |
19,8 |
- 13.9 |
3.74 |
298-1500 K |
Naftaleno |
-13.02 |
185.0 |
-126.0 |
31.90 |
298-1500 K |
Cloropreno |
2.93 |
75.6 |
-48.3 |
11.80 |
298-1500 K |
Ciclobutano |
-9.00 |
105.0 |
-62.9 |
14.50 |
298-1500 K |
Clorobenceno |
- 5.97 |
123.0 |
- 88.9 |
24.10 |
298-1500 K |
Anilina |
-8.11 |
143.4 |
-107.0 |
30.70 |
298-1500 K |
Fenol |
-5.68 |
126.0 |
- 85.4 |
20.50 |
298-1500 K |
n-Butanol |
-2.51 |
91.1 |
- 39.6 |
4.09 |
298-1500 K |
Oxido de propileno |
- 3.57 |
86.4 |
- 61.6 |
18.50 |
298-1500 K |
Oxido de butileno |
- 2.81 |
97.9 |
- 48.6 |
6.10 |
298-1500 K |
Tabla 3-9. CONSTANTES PARA LAS ECUACIONES: cp =a + bT + c T2 , y cp= 7.95 + u Tv
COMPUESTO |
A |
b x 103 |
- c x 106 |
u |
V |
Metano |
3.42 |
9.91 |
1.28 |
6.4 x 10-12 |
4.00 |
E tile no |
2.71 |
16.20 |
2.80 |
8.13 x 10-11 |
3.85 |
Etano |
138 |
23.25 |
4.27 |
6.20 x 10-5 |
1.79 |
Propileno |
1.97 |
27.69 |
5.25 |
2.57 x 10-3 |
1.26 |
Propano |
0.41 |
35.95 |
6.97 |
3.97 x 10-3 |
1.25 |
n-Butano |
2.25 |
45.40 |
8.83 |
0.93 x 10-2 |
1.19 |
iso-Butano |
2.30 |
45.78 |
8.89 |
0.93 x lO-2 |
1.19 |
Pentano |
3.14 |
55.85 |
10.98 |
3.90 x 10-2 |
1.00 |
|